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Modelling diagenetic reactions and secondary porosity generation in sandstones controlled by the advection of low-molecular-weight organic acids

发布时间:2025-03-12 点击次数:

影响因子: 2.8
DOI码: 10.1111/bre.12860
发表刊物: Basin Research
摘要: Higher secondary porosity was observed in the centre of a sandstone unit in the Eocene Shahejie Formation fan delta front sandstones from the Bozhong Depression, Bohai Bay Basin. This differs from past studies showing secondary porosity mainly in the marginal parts of sandstones adjacent to shales. This study utilized reactive transport models involving low-molecular-weight organic acids (LMWOA) to discuss potential processes resulting in the contrary distribution of secondary porosity. An interface model simulating LMWOA diffusion from adjacent shales to the sandstone resulted in secondary porosity in sandstones adjacent to shales. In contrast, an advection model simulating advective transport of LMWOA parallel to the sandstone bedding successfully generated higher secondary porosity in the central part. The central part of the sandstone exhibited better grain sorting (greater depositional porosity) and significantly less early carbonate cements compared to the marginal sandstone parts. Consequently, the central part had greater porosity prior to the dissolution through LMWOA. The initially higher porosity in the central part allowed for a higher advective flux of LMWOA-rich water and associated lower pH, resulting in decreased oligoclase saturation, higher oligoclase dissolution rates and ultimately higher secondary porosity. This study indicates that grain sorting during sediment deposition, early carbonate cementation, LMWOA production in adjacent shales, and advection processes collectively control the diagenetic reactions and the distribution of secondary porosity in sandstones.
论文类型: 期刊论文
论文编号: 额2860
学科门类: 理学
卷号: 36
期号: 2
发表时间: 2024-04-01
收录刊物: SCI
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