DOI number:

10.1016/j.marpetgeo.2023.106164

Journal:

Marine and Petroleum Geology

Key Words:

Formation water；Formation water reconstruction；Water-rock interaction；Hydrocarbon biodegradation；Salinity enrichment；Salinity reversal；Smectite-illite transformation

Abstract:

Formation waters from the Huanghekou Sag, offshore Bohai Bay Basin, exhibited two depth zones with elevated total dissolved solid (TDS) composition. The shallow diagenetic zone at a depth of ∼1200–2000 m (∼45–70 °C) and the deep diagenetic zone at a depth of ∼3000–4000 m (∼100–130 °C) have TDS concentrations exceeding 70,000 mg/L, while the depth interval in between the two zones has TDS concentrations lower than 35,000 mg/L. Isometric log-ratio interpretations of the reconstructed formation water compositions, crude oil compositions, stable hydrogen and oxygen isotopes, light microscopy and clay mineral analysis were used to interpret the origins of the two diagenetic depth zones. Formation waters within each stratigraphic unit were dominantly composed of Na–K–Cl type. Processes affecting the deep diagenetic zone were attributed to (1) the dissolution of halite, albite and albitization, which predominantly caused the TDS enrichment, and (2) the dilution of TDS caused by the inter-layer H2O released from the transformation of smectite to illite (salinity reversal at depths > ∼3500 m). In comparison, the enrichment in TDS in the shallow diagenetic zone was attributed to hydrocarbon biodegradation, which consumed free water. The crude oil composition indicates severe hydrocarbon biodegradation. Biodegradation of low-molecular-weight organic carbons such as hexadecane (through methanogenesis) and benzene (through microbial sulfate reduction) could consume sufficient H2O to enrich TDS to the observed levels. At the same time, relatively constant Na/Cl and Ca/Cl ratios versus TDS can be explained by water consumption as well. This work could serve as a reference for the interpretation of two diagenetic zones characterised by distinct TDS enrichments in other hydrocarbon-bearing sedimentary basins.

Indexed by:

Journal paper

Document Code:

106164

Discipline:

Natural Science

Volume:

150

Date of Publication:

2023-04-01

Included Journals:

SCI