副教授
发布时间：2024-08-06
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| DOI码： | 10.1016/j.inoche.2020.108336 |
| 所属单位： | Yangtze University |
| 发表刊物： | Inorganic Chemistry Communications |
| 项目来源： | the National Natural Science Foundation of China (21303008) and Natural Science Foundation of Hubei |
| 关键字： | n-Propyltriethoxysilane, Mesoporous TiO2-SiO2, Bulky sulfur compound, Oxidative desulfurization. |
| 摘要： | Amorphous mesoporous TiO2-SiO2 composites have been prepared by introducing n-propyltriethoxysilane (PTES) into the synthesis system of titanium silicalite-1 (TS-1). The hydrolysate of PTES can participate in the condensation between ‘Si(OH)4’ and ‘Ti(OH)4’, and generate the isolated ‘alkyl-rich regions’ and ‘inorganic TiO2-SiO2 regions’. Proper amount of ‘alkyl rich regions’ can highly separate titania–silica species and seriously retard the crystal growth, thereby producing the amorphous mesoporous structure. As the PTES/Si molar ratio is between 0.1 and 0.2, the resulting samples have plenty of three-dimensional connected mesopores, and they display outstanding catalytic performance in the oxidative desulfurization of bulky sulfur compounds. |
| 论文类型： | 期刊论文 |
| 通讯作者： | 刘小雨，刘晓雪，单金灵，怀敬龙，杨欢，颜学敏，郑延成，李颢* |
| 论文编号： | 108336 |
| 卷号： | 123 |
| 发表时间： | 2021-01-01 |
| 收录刊物： | SCI |
